A drop-on-demand printing method comprising performing the following steps in a printing head: discharging a first primary drop of a first liquid from a first nozzle outlet to move along a first path (pA) with a first speed; discharging a second primary drop of a second liquid from a second nozzle outlet to move along a second path (pB) with a second speed, lower than the first speed, wherein the second path (pB) is inclined with respect to the first path (pB) along an axis inclined at an angle (α) from 3 to 60 degrees and crosses the first path (pA) at a connection point; controlling the flight of the first primary drop and the second primary drop to combine the first primary drop with the second primary drop into a combined drop at the connection point so that a chemical reaction is initiated between the first liquid of the first primary drop and the second liquid of the second primary drop; applying electric charge to the combined drop; wherein the path of flight (pC) of the combined drop is altered no more than 20 degrees from the axis of the path of flight (pA) of the first primary drop; and controlling the path of flight (pC) of the combined drop with applied electric charge by deflecting electrodes.