Invention Grant
- Patent Title: Process for producing multimodal polyethylene in-situ blends including ultra-high molecular weight fractions
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Application No.: US15539130Application Date: 2015-12-21
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Publication No.: US10669410B2Publication Date: 2020-06-02
- Inventor: Yi Liu , Qizheng Dou , Alexandra Romina Albunia
- Applicant: BOREALIS AG
- Applicant Address: AT Vienna
- Assignee: BOREALIS AG
- Current Assignee: BOREALIS AG
- Current Assignee Address: AT Vienna
- Agency: Insigne LLP
- Priority: com.zzzhc.datahub.patent.etl.us.BibliographicData$PriorityClaim@2dc01063
- International Application: PCT/EP2015/002587 WO 20151221
- International Announcement: WO2016/102061 WO 20160630
- Main IPC: C08L23/08
- IPC: C08L23/08 ; C08L23/06 ; C08F10/02 ; B29B9/12 ; C08F2/00 ; B29B9/06

Abstract:
The present application relates to a process for producing a multimodal polyethylene composition comprising the steps of polymerizing a polyethylene fraction (A-1) having a weight average molecular weight Mw of equal to or more than 500 kg/mol to equal to or less than 10,000 kg/mol and a density of equal to or more than 915 kg/m3 to equal to or less than 960 kg/m3 in one reaction step and polymerizing a polyethylene fraction (A-2) having a lower weight average molecular weight Mw as polyethylene fraction (A-1) and a density of equal to or more than 910 kg/m3 to equal to or less than 975 kg/m3 in a second reaction step of a sequential multistage process wherein one of said polyethylene fractions is polymerized in the presence of the other of said polyethylene fractions to form a first polyethylene resin (A) having a weight average molecular weight Mw of equal to or more than 150 kg/mol to equal to or less than 1,500 kg/mol, and a density of equal to or more than 910 kg/m3 to equal to or less than 975 kg/m3, wherein the weight average molecular weight Mw of the first polyethylene resin (A) is lower than the weight average molecular weight Mw of the polyethylene fraction (A-1), blending the first polyethylene resin (A) with a second polyethylene resin (B) having a weight average molecular weight Mw of equal to or more than 50 kg/mol to less than 500 kg/mol, and a density of equal to or more than 910 kg/m3 to equal to or less than 970 kg/m3 to form said multimodal polyethylene composition, wherein the multimodal polyethylene composition a melt flow rate MFR5 (190° C., 5 kg) of 0.01 to 10 g/10 min and a density of equal to or more than 910 kg/m3 to equal to or less than 970 kg/m3 a polyethylene composition obtainable by said process and the polyethylene resin of said first polymerization step.
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