Invention Grant
- Patent Title: Highly fluorescent pyrrole-BF2 chromophores
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Application No.: US16229368Application Date: 2018-12-21
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Publication No.: US10676489B2Publication Date: 2020-06-09
- Inventor: Christopher J. Ziegler , Ingrid-Suzy Tamgho
- Applicant: Christopher J. Ziegler , Ingrid-Suzy Tamgho
- Applicant Address: US OH Akron
- Assignee: The University of Akron
- Current Assignee: The University of Akron
- Current Assignee Address: US OH Akron
- Agency: Renner, Kenner, Greive, Bobak, Taylor & Weber
- Main IPC: C07F5/02
- IPC: C07F5/02 ; C09B23/10 ; C09B23/16 ; C09B55/00 ; C09K9/02 ; C12Q1/00 ; C09B57/00 ; H01G9/20 ; H01L51/00

Abstract:
Fluorescent chromophores nicknamed BOPHY are provided. The chromophores may be readily synthesized in two steps from readily available reagents via the coupling of a pyrrole aldehyde or ketone with hydrazine, followed by reaction with BF3. The resultant symmetric and dimeric tetracycle is comprised of two BF2 units in six-member chelate rings, appended by pyrrole units on the periphery. The quantum yield of fluorescence for the unmodified compound and the tetramethyl variant are near unity, with values 95 and 92% respectively in CH2Cl2.
Public/Granted literature
- US20190119305A1 HIGHLY FLUORESCENT PYRROLE-BF2 CHROMOPHORES Public/Granted day:2019-04-25
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