There is provided an ink set for ink-jet printing comprising an aqueous ink and a reaction liquid, wherein the aqueous ink contains an emulsion, a surfactant, an organic solvent, a pigment, and water, the reaction liquid contains an aggregating agent, 1,2-alkanediol, a glycol ether-based solvent and/or a glycol ether acetate-based solvent, and water, and the emulsion has a glass transition temperature of 50° C. or higher. The ink set for ink-jet printing is provided with an aqueous ink excellent in the discharge stability, and can form an image excellent in coated film properties such as the rubbing resistance and the adherence.