Crosslinked organopolysiloxane and method for producing same, mist suppressant, and solvent-free silicone composition for release paper
Abstract:
Provided are: a crosslinked organopolysiloxane which has properties intermediate between a dimethylpolysiloxane oil and a gel-like crosslinked siloxane; and a method for producing the crosslinked organopolysiloxane. An oil-like organopolysiloxane which is produced by: adding a compound having a siloxane unit represented by formula (3) to a gel-like silicone, wherein the gel-like silicone is produced by a hydrosilylation reaction of an organopolysiloxane having an alkenyl group with an organohydrogenpolysiloxane having a hydrogen atom bonded to a silicon atom in the presence of a platinum-group metal catalyst; and then equilibrating the resultant product with an acid or alkali catalyst. R12SiO2/2  (3) (R1 represents a group selected from a monovalent hydrocarbon group having no aliphatic unsaturated bond and an alkenyl group represented by the formula: —(CH2)a—CH═CH2 (wherein a represents a numerical value of 0 to 6), and the average polymerization degree of formula (3) is 3 to 2,000).
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