A method of manufacturing a short-preventive all-solid-state battery in which a thermosetting insulating resin applied in advance to a pouch-type electrode case provided with an electrode assembly received therein is forced to fill a space between the edges of the electrode assembly during packaging of the electrode assembly to fill vacant spaces between electrodes at the edges of the electrode assembly and may thus prevent physical contact and collision between the electrodes and fundamentally prevent generation of a short circuit caused thereby.