A vehicle window structure for preventing a person from being thrown out, applied to a vehicle, includes a fixing frame. An inner frame surface of the fixing frame is provided with a plurality of fixing portions spaced apart from each other. An arresting net includes at least one plastic rope fixedly connected to the fixing portions in an interlaced manner. The fixing frame is provided with a light-permeable unit that is mounted and fixed within the inner frame surface and covers the arresting net. When the vehicle has an accidental rollover unfortunately, even if the light-permeable unit is damaged or the fixing frame is deformed during the overturning of the vehicle, the arresting net is still able to arrest the user effectively because the arresting net is directly fixed to the fixing frame, thereby preventing the user from being thrown out of the vehicle.