Invention Grant
- Patent Title: Process for methylating aromatic hydrocarbons
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Application No.: US16336034Application Date: 2017-09-12
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Publication No.: US10696608B2Publication Date: 2020-06-30
- Inventor: Todd E. Detjen , Tan-Jen Chen , Brett T. Loveless , Robert G. Tinger
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- International Application: PCT/US2017/051179 WO 20170912
- International Announcement: WO2018/067281 WO 20180412
- Main IPC: C07C2/00
- IPC: C07C2/00 ; C07C2/86 ; B01J29/70 ; B01J8/02 ; C07C5/27

Abstract:
In a process for producing paraxylene, a hydrocarbon feedstock comprising benzene and/or toluene is contacted with an alkylating reagent comprising methanol and/or dimethyl ether in an alkylation reaction zone under alkylation conditions in the presence of an alkylation catalyst to produce an alkylated product comprising xylenes. The alkylation catalyst comprises a molecular sieve having a Constraint Index ≤5, and the alkylation conditions comprise a temperature less than 500° C. At least part of the alkylated product is supplied to a paraxylene recovery unit to recover paraxylene and produce a paraxylene-depleted stream, which is then contacted with a xylene isomerization catalyst under conditions effective to isomerize xylenes in the paraxylene-depleted stream and produce an isomerized stream having a higher concentration of paraxylene than the paraxylene-depleted stream. At least part of the isomerized stream is then recycled to the paraxylene recovery unit to recover the paraxylene therein.
Public/Granted literature
- US20190218159A1 Process for Methylating Aromatic Hydrocarbons Public/Granted day:2019-07-18
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