The present invention provides solid oxide cells such as fuel cells, electrolyzers, and sensors comprising an electrolyte having an interface between an yttria-stabilized zirconia material and a glass material, in some embodiments. Other embodiments add an interface between a platinum oxide material and the yttria-stabilized zirconia material in the electrolyte. Further embodiments of solid oxide cells have an ion-conducting species such as an ionic liquid or inorganic salt in contact with at least one electrode of the cell. Certain embodiments provide room temperature operation of solid oxide cells.