The present invention relates to a potential difference-based diversion electrode arrangement and field intensity compensation method, comprising the following steps: the arrangement positions of paired diversion electrodes are determined according to the difference of potential around a position of field intensity to be compensated and the direction of an electric field line, and the paired diversion electrodes are inserted; and the field intensity enhancement rate of the position of field intensity to be compensated and the compensated field intensity value are calculated according to the difference of potential and arrangement positions of the paired diversion electrodes. In the present invention, the paired diversion electrodes are arranged in the direction of the electric field line by using the spatial difference of potential in the electric field, and the compensation of local field intensity is implemented, thereby beneficial to improving the overall efficiency of electrokinetic remediation for organic contaminated soil, and reducing the spatial difference of remediation efficiency.