Coated optical fibers and uses of such fibers as sensors in high temperature and/or high pressure environments. The coated optical fiber has improved sensing properties at elevated pressure and/or temperature, such as enhanced acoustic sensitivity and/or a reduced loss in acoustic sensitivity. The use of the coated optical fibers in various sensing applications that require operation under elevated pressure and/or temperature, such as, acoustic sensors for various geological, security, military, aerospace, marine, and oil and gas applications are also provided.