Hexagonal Boron Nitride (hBN) is a synthetic material that may be used in several applications due to its chemical inertness, thermal stability, and other beneficial properties. hBN composite materials and method for making such composites are described here. In particular composite materials including both functionalized hBN and cement or cementitious materials and methods for making the same are discussed. Such materials may be useful for construction, well cementing (both primary and remedial cementing), nuclear industry, 3D printing of advanced multifunctional composites, and refractory materials.