Invention Grant
- Patent Title: Process to make tubular ethylene based polymers with high G′ and broad MWD
-
Application No.: US15736921Application Date: 2016-06-23
-
Publication No.: US10730977B2Publication Date: 2020-08-04
- Inventor: Otto J. Berbee , Stefan Hinrichs , Sean W. Ewart , John O. Osby
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agency: Quarles & Brady LLP
- International Application: PCT/US2016/039061 WO 20160623
- International Announcement: WO2016/210160 WO 20161229
- Main IPC: C08F210/02
- IPC: C08F210/02 ; C08F2/01 ; C08F2/38 ; C08F10/02 ; C08F2/00 ; C08K5/07 ; C08K5/101 ; C08F210/16

Abstract:
A process to form an ethylene-based polymer comprises polymerizing a reaction mixture comprising ethylene, at least one symmetrical polyene and at least one chain transfer agent system comprising at least one chain transfer agent (CTA) in the presence of at least one free-radical initiator and in a reactor configuration comprising at least two reaction zones, reaction zone 1 and reaction zone i (i≥2), wherein reaction zone i is downstream from reaction zone 1. The ratio of “the activity of the CTA system of the feed to the first reaction zone” to the “activity of the CTA system of the cumulative feed to the reaction zone i,” (Z1/Zi), is less than or equal to (0.8−0.2*log(Cs)), wherein Cs is from 0.0001 to 10.
Public/Granted literature
- US20180171047A1 Improved Process to Make Tubular Ethylene Based Polymers with High G' and Broad MWD Public/Granted day:2018-06-21
Information query