A combustion gas particle adhesion prevention boiler includes a furnace for containing a combustion gas and passing an exhaust gas; a dust collector for collecting combustion gas particles present in the exhaust gas; a combustion unit for combusting fuel and injecting a flame generated by the combustion into the furnace in order to generate the combustion gas; and a voltage application unit for negatively charging the fuel. The combustion gas particle adhesion prevention boiler, and a method using the same, prevent combustion gas particles generated by the combustion of fuel from being adhered to a tube, the inner wall of a furnace, etc., by applying a negative voltage to the combustion unit, and applying a positive voltage to a dust collector, such that the negatively charged combustion gas particles can be easily collected in the dust collector by the attractive force with the positively charged dust collector.