A light valve structure, a manufacturing method therefor, an operating method therefor, an array substrate and an electronic device are provided. The light valve structure includes a base substrate, a light-transmissive part and a light-shielding part. The light-transmissive part is disposed on the base substrate and light-transmissive, and it at least includes a first electrode. The light-shielding part is disposed on the light-transmissive part; a first end of the light-shielding part is fixed relative to the light-transmissive part; and the light-shielding part includes a base layer and a second electrode layered on the base layer. The light-shielding part is configured to be curled so as to be away from the light-transmissive part, and/or the light-shielding part is configured to be spread due to the mutual adsorption between the first electrode and the second electrode, so as to be superimposed on the light-transmissive part.