Invention Grant
- Patent Title: Catalytic preform system comprising a rare earth metallocene
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Application No.: US15780233Application Date: 2016-11-30
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Publication No.: US10752712B2Publication Date: 2020-08-25
- Inventor: Vincent Lafaquiere , Julien Thuilliez
- Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
- Applicant Address: FR Clermont-Ferrand
- Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
- Current Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
- Current Assignee Address: FR Clermont-Ferrand
- Agency: Dickinson Wright PLLC
- Priority: com.zzzhc.datahub.patent.etl.us.BibliographicData$PriorityClaim@5059e95d
- International Application: PCT/FR2016/053137 WO 20161130
- International Announcement: WO2017/093654 WO 20170608
- Main IPC: C08F210/02
- IPC: C08F210/02 ; C08F236/06 ; C08F4/52 ; C08F4/64

Abstract:
A catalytic system based at least on a preformation conjugated diene monomer, on an organometallic compound as cocatalyst and on a metallocene of formula {P(Cp1)(Cp2)Y} is provided. In the formula, Y denotes a group comprising a metal atom which is a rare earth metal, Cp1 and Cp2, which are identical or different, are selected from the group consisting of fluorenyl groups, cyclopentadienyl groups and indenyl groups, the groups being substituted or unsubstituted, and P is a group bridging the two Cp1 and Cp2 groups and comprising a silicon or carbon atom. Such a catalytic system exhibits an improved stability of the catalytic activity over time, in particular on storage.
Public/Granted literature
- US20180355083A1 CATALYTIC PREFORM SYSTEM COMPRISING A RARE EARTH METALLOCENE Public/Granted day:2018-12-13
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