Production method for ion exchange membrane for alkali chloride electrolysis, and production method for alkali chloride electrolysis apparatus
Abstract:
To provide a production method whereby an ion exchange membrane for alkali chloride electrolysis can be obtained which has high current efficiency, little variation in current efficiency and high alkaline resistance. This is a method for producing an ion exchange membrane 1 having a layer (C) 12 containing a fluorinated polymer (A) having carboxylic acid type functional groups, by immersing an ion exchange membrane precursor film having a precursor layer (C′) containing a fluorinated polymer (A′) having groups convertible to carboxylic acid type functional groups, in an aqueous alkaline solution comprising an alkali metal hydroxide, a water-soluble organic solvent and water, and converting the groups convertible to carboxylic acid type functional groups to carboxylic acid functional groups, wherein the concentration of the water-soluble organic solvent is from 1 to 60 mass % in the aqueous alkaline solution (100 mass %); the temperature of the aqueous alkaline solution is at least 40° C. and less than 80° C.; and the proportion of structural units having carboxylic acid type functional groups in the fluorinated polymer (A) is from 13.0 to 14.50 mol % in all structural units (100 mol %) in the fluorinated polymer (A).
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