A secondary battery having a three-dimensional (“3D”) structure with a curvature and a method of manufacturing the same are provided. The secondary battery includes a 3D electrode structure, and a first collector layer and a second collector layer, which are disposed on the 3D electrode structure. The 3D electrode structure is curved in a thickness direction thereof to have a curvature, and the first collector layer and the second collector layer have a curvature corresponding to the curvature of the 3D electrode structure.