The present invention provides a composition used for manufacturing gloves comprising polyacrylate, which has glass transition temperature (Tg) under −20° C. The composition comprises characteristics of anti-sticking feature, alcohol resistance, anti-bacteria, anti-mildew, anti-UV, and without allergen. The gloves made by the composition can replace those made by traditional materials such as NBR, PVC, and so on. The composition used for gloves is able to apply to medical and electronics industries.