A method for treating wastewater containing fluoroquinolone antibiotics by activating peroxyacetic acid heterogeneously with lanthanum ruthenate perovskite (LaRuO3) catalyst. The method includes: adding peroxyacetic acid to wastewater containing ciprofloxacin, mixing to obtain a peroxyacetic acid solution, adjusting a pH of the peroxyacetic acid solution; and adding lanthanum ruthenate perovskite to the peroxyacetic acid solution to obtain a mixed solution, and stirring the mixed solution in a constant temperature shaker, and removing the ciprofloxacin at a normal temperature.