The present disclosure relates to a method and system for automating execution of processes by a process automation system. The process automation system captures environment data and application data associated with at least one of applications and systems which are utilized for performing a process and records each of user actions performed on at least one of the applications and the systems with reference to the environment data. The process automation system determines one or more automation rules for each set of connected user actions within and between the at least one of the applications and the systems from the recorded user actions for execution of a corresponding activity in the process and creates an execution sequence comprising the one or more automation rules for automating the process.