One variation of a method for identifying a user entering an autonomous vehicle includes: receiving a ride request from the user, the ride request specifying a pickup location; at the autonomous vehicle, autonomously navigating to the pickup location, scanning a field near the autonomous vehicle for a human approaching the autonomous vehicle, and, in response to detecting the human proximal the autonomous vehicle, recording an image of the human; detecting a face of the human in the image; accessing a faceprint characterizing facial features of the user; and, in response to the face of the human detected in the image exhibiting features represented in the faceprint, identifying the human as the user and triggering a door of the autonomous vehicle to unlock for the user.