Methods, systems, and techniques are provided for acquiring fuel cell polarization data, obtaining fuel cell polarization parameters from the fuel cell polarization data, and validating the reliability of the obtained data and parameters. In some aspects methods for acquiring and parameterizing proton exchange membrane fuel cell polarization data include measuring at least one current-voltage point for an operating fuel cell, and determining at least one polarization parameter of the fuel cell by evaluating a closed form solution using the at least one current-voltage point.