Embodiments relate to multilayer structures, multilayer films, and packages formed therefrom. As an example, a multilayer structure can include a multilayer structure comprising a polyolefin sealant layer, a coupling layer on the polyolefin sealant layer, where the coupling layer includes a polyolefin and a maleic anhydride grafted (MAH) polymer, where the total amount of MAH polymer is from 15 weight percent to 50 weight percent of a total weight percent of the coupling layer, where the polyolefin is selected from the group consisting of a high pressure low density polyethylene, a high density polyethylene, an ethylene acrylic acid copolymer, an ethylene(meth)acrylic acid copolymer, propylene based plastomers, ionomers or a combination thereof, and a barrier layer directly on the coupling layer.