- Patent Title: Polyphenylsulfone-based proton conducting polymer electrolyte, proton conducting solid polymer electrolyte membrane, electrode catalyst layer for solid polymer fuel cells, method for producing electrode catalyst layer for slid polymer fuel cells, and fuel cell
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Application No.: US15744640Application Date: 2016-07-29
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Publication No.: US10862151B2Publication Date: 2020-12-08
- Inventor: Jedeok Kim , Yaojian Zhang
- Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
- Applicant Address: JP Tsukuba
- Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
- Current Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCE
- Current Assignee Address: JP Tsukuba
- Agency: Brinks Gilson & Lione
- Priority: JP2015-160418 20150817
- International Application: PCT/JP2016/072350 WO 20160729
- International Announcement: WO2017/029967 WO 20170223
- Main IPC: H01M8/1027
- IPC: H01M8/1027 ; H01M8/1032 ; C08G75/23 ; C08G65/38 ; C08L81/06 ; H01M4/88 ; H01M8/1039 ; H01M8/1018 ; H01M4/86 ; H01M8/1023 ; C08L45/00 ; C08L71/12 ; C08L81/08 ; G01R33/46 ; H01M8/1025 ; H01M8/103

Abstract:
The present invention addresses the problem of providing a crosslinked film and a hydrocarbon-based proton conducting solid electrolyte having a proton conductivity equal to that of a perfluorosulfonate ion exchange polymer. Disclosed as a means for solving this problem is a proton conducting polymer electrolyte which is composed of a sulfonated polyphenyl compound having a plurality of repeating units, and wherein two or more (for example, four or six) sulfonic groups are introduced into one repeating unit on average. The sulfonated polyphenyl compound may be a polymer or copolymer having a skeleton structure selected from among a polyaryl sulfide, a polyaryl ether, a polyarylsulfone, a polyarylketone and a polyaryl hexafluoroisopropylidene. A proton conducting solid polymer electrolyte membrane is able to be produced by shaping this proton conducting polymer electrolyte into a film form and crosslinking this proton conducting polymer electrolyte via sulfonic groups.
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