Polyphenylsulfone-based proton conducting polymer electrolyte, proton conducting solid polymer electrolyte membrane, electrode catalyst layer for solid polymer fuel cells, method for producing electrode catalyst layer for slid polymer fuel cells, and fuel cell
Abstract:
The present invention addresses the problem of providing a crosslinked film and a hydrocarbon-based proton conducting solid electrolyte having a proton conductivity equal to that of a perfluorosulfonate ion exchange polymer. Disclosed as a means for solving this problem is a proton conducting polymer electrolyte which is composed of a sulfonated polyphenyl compound having a plurality of repeating units, and wherein two or more (for example, four or six) sulfonic groups are introduced into one repeating unit on average. The sulfonated polyphenyl compound may be a polymer or copolymer having a skeleton structure selected from among a polyaryl sulfide, a polyaryl ether, a polyarylsulfone, a polyarylketone and a polyaryl hexafluoroisopropylidene. A proton conducting solid polymer electrolyte membrane is able to be produced by shaping this proton conducting polymer electrolyte into a film form and crosslinking this proton conducting polymer electrolyte via sulfonic groups.
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