Disclosed are examples of luminaires that provide light for general illumination and treat air via a biofilter. In the examples, a luminaire may include a light source configured to illuminate a space, a biofilter configured to treat air, and an air circulation system. The light source may be configured to illuminate a space in which the luminaire is located with general illumination light. The biofilter may include an air permeable membrane, a substrate, and a microorganism that treats air that comes in contact with the microorganism. The air circulation system is configured to draw air into contact with the biofilter and output air treated by contact with the biofilter into at least a portion of the space illuminated by the light source.