A method for TDMA slot synchronization and calibration of a master and a slave includes: receiving a synchronizing frame from the master by the slave, wherein the synchronizing frame includes a first count value of a timing counter of the master; analysing the synchronizing frame by the slave to acquire the first count value; and adjusting a TDMA slot of the slave according to the first count value and a second count value of a timing counter of the slave to synchronize the TDMA slot of the slave with a TDMA slot of the master.