A composition including a polymer including at least one of an amic acid structural unit and an imide structural unit and an inorganic particle surface-treated with a compound represented by Chemical Formula 1, a polymer-inorganic particle nanocomposite prepared using the composition an article and an optical device including the article: In Chemical Formula 1, R1 to R4 are independently a C1 to C30 alkyl group, a C3 to C10 cycloalkyl group, a C6 to C30 aryl group, or a combination thereof, and n is an integer of 1 or more.