A dual-feed loop antenna structure adapted to be disposed on a substrate includes two loop antennas and two open-loop grounding radiators. Each of the loop antennas is used for resonating at a first frequency band and a second frequency band and includes a feed-in end and a ground segment. The two open-loop grounding radiators are located between the two loop antennas. Each of the open-loop grounding radiators extends from the ground segment of the corresponding loop antenna. A coupling gap is formed between the two open-loop grounding radiators. One of the loop antennas and the open-loop grounding radiator connected thereto completely overlap the other loop antenna and the other open-loop grounding radiator connected thereto after being mirrored and reversed. An electronic device is further provided.