In one aspect, the disclosure relates to processes for preparation of a carbon foam material, the process comprising heating in a microwave heating apparatus a mixture comprising a coal material and a flux agent. In other aspects, relates to processes for preparation of a carbon foam material, the process comprising heating in a microwave heating apparatus a mixture comprising a coal material, a foaming pitch material and a flux agent. In a further aspect, the mixture comprising a coal material, a foaming pitch material and a flux agent after heating in the microwave heating apparatus can form a pseudo-fluid material. In a still further aspect, the pseudo-fluid material can be arranged in mold, and then further heated to form a carbon foam. The disclosure, in further aspects, relates to processes further providing carbon materials such as carbon composite materials, graphite, graphite flakes, and graphene. In various aspects, the disclosure relates to the carbon foam and other materials prepared using the disclosed processes. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.