Invention Grant
- Patent Title: Process for continuously preparing n-butyl acrylate or isobutyl acrylate
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Application No.: US16636703Application Date: 2018-08-13
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Publication No.: US10941103B2Publication Date: 2021-03-09
- Inventor: Ortmund Lang , Tim Blaschke , Christian Raith , Michael Schafranka , Claus Hechler
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen am Rhein
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen am Rhein
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP17186691 20170817
- International Application: PCT/EP2018/071863 WO 20180813
- International Announcement: WO2019/034577 WO 20190221
- Main IPC: C07C67/08
- IPC: C07C67/08 ; C07C67/54 ; C07C67/58 ; C07C69/54

Abstract:
A process for continuously preparing a butyl acrylate H2C═CH—C(═O)OR, with R=n-butyl or isobutyl, wherein aqueous 3-hydroxypropionic acid is converted under dehydrating and esterifying conditions in the presence of the corresponding butanol R—OH in a reactor with a rectification column and butyl acrylate formed, unconverted butanol and water used and formed are distilled off overhead as a ternary azeotrope, after separation into a liquid aqueous phase and liquid organic phase each of the aqueous and organic phases is at least partly discharged, and the organic phase comprising the butyl acrylate and the butanol is subjected to distillative separation.
Public/Granted literature
- US20200239400A1 PROCESS FOR CONTINUOUSLY PREPARING N-BUTYL ACRYLATE OR ISOBUTYL ACRYLATE Public/Granted day:2020-07-30
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