In accordance with embodiments of the present disclosure, systems and methods for triggering detonation of a perforating gun via optical signals are provided. An improved laser firing head may be used with an optical cable (e.g., fiber optic cable) run through the wellbore to trigger detonation of a perforating gun in response to an optical signal. The laser firing head may be activated, and the perforating gun fired, upon the application of an optical signal output from the surface and transmitted through the optical cable. The disclosed system using the laser firing head with the optical cable may be impervious to electrical interference, since the laser firing head may only fire the perforating gun when a properly modulated laser or light source is directed down the optical cable for a specific period of time.