An electric response infrared reflection device and a preparation method thereof. The device comprises three light-transmitting conductive substrates which are oppositely arranged. Two adjacent light-transmitting conductive substrates of the three light-transmitting conductive substrates are respectively packaged to form a first adjusting area and a second adjusting area. Both the first adjusting area and the second adjusting area are filled with liquid crystal layers. Each of the liquid crystal layers comprises a mixed liquid crystal material. The mixed liquid crystal material comprises a chiral nematic phase liquid crystal, a monomer, a photoinitiator, and a chiral dopant. The spiral direction of the chiral nematic phase liquid crystal in the first adjusting area is opposite to the spiral direction of the chiral nematic phase liquid crystal in the second adjusting area, so that the total reflection of an infrared band can be implemented.