Methods and systems are provided for conducting an evaporative emissions test diagnostic on a vehicle fuel system and evaporative emissions control system during engine-on conditions. In one example, a first fuel vapor storage device is separated from a second fuel vapor storage device by a one-way check valve, thus preventing loading of the first fuel vapor storage device during conditions such as refueling operations, diurnal temperature fluctuations, or from running-loss vapors from a vehicle fuel tank. In this way, the evaporative emissions test diagnostic may be conducted during a cold-start event where an exhaust catalyst is below a predetermined threshold temperature required for catalytic oxidation of hydrocarbons in the engine exhaust, without increasing undesired exhaust emissions.