- Patent Title: Transition metal-containing composite hydroxide and production method thereof, and production method of positive electrode active material for nonaqueous electrolyte secondary battery
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Application No.: US16461072Application Date: 2017-11-21
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Publication No.: US11024839B2Publication Date: 2021-06-01
- Inventor: Takahiro Toma , Hiroko Senba , Taira Aida , Tetsufumi Komukai
- Applicant: SUMITOMO METAL MINING CO., LTD.
- Applicant Address: JP Tokyo
- Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee: SUMITOMO METAL MINING CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Katten Muchin Rosenman LLP
- Priority: JPJP2016-226872 20161122
- International Application: PCT/JP2017/041849 WO 20171121
- International Announcement: WO2018/097136 WO 20180531
- Main IPC: H01M4/36
- IPC: H01M4/36 ; C01G53/00 ; C01G53/04 ; C30B7/14 ; C30B29/22 ; H01M4/485 ; H01M4/505 ; H01M4/525 ; H01M10/0525 ; H01M4/02

Abstract:
A transition metal-containing composite hydroxide comprises secondary particles having: a center portion of fine primary particles; and an outer-shell portion having a high-density layer of plate-shaped primary particles formed outside the center portion, a low-density layer of the fine primary particles formed outside the high-density layer, and an outer-shell layer of the plate-shaped primary particles formed outside the low-density layer. The composite hydroxide is obtained by a method comprising a nucleation step in an oxidizing atmosphere and a particle growth step, the particle growth step comprising: a first stage of maintaining the oxidizing atmosphere; a second stage of switching to and maintaining a non-oxidizing atmosphere; a third stage of switching again to and maintaining the oxidizing atmosphere; and a fourth stage of switching again to and maintaining the non-oxidizing atmosphere.
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