Invention Grant
- Patent Title: Processes to produce poly alpha-olefin trimer and apparatus therefor
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Application No.: US16537381Application Date: 2019-08-09
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Publication No.: US11028197B2Publication Date: 2021-06-08
- Inventor: Patrick C. Chen , Mark H. Li , Jennifer L. Rapp , Pramod J. Nandapurkar , Brian H. Wahn , Babak LotfizadehDehkordi , Craig J. Emett , Najeeb M. Kuzhiyil , Jian Yang
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C07C2/30
- IPC: C07C2/30 ; C07C2/32 ; C08F4/6592 ; C08F210/16 ; C08F4/659

Abstract:
In at least one embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin to a first catalyst system comprising activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The first alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes at least 60 wt % of PAO dimer and 40 wt % or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more. The process includes introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition including an acid catalyst in a second reactor to form a second reactor effluent comprising PAO trimer.
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