Invention Grant
- Patent Title: Method for obtaining pure 1,3-butadiene
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Application No.: US16475566Application Date: 2018-01-24
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Publication No.: US11034631B2Publication Date: 2021-06-15
- Inventor: Bernd Heida , Tobias Keller , Jan-Oliver Weidert
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen am Rhein
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen am Rhein
- Agency: Grüneberg and Myers PLLC
- Priority: EP17153120 20170125
- International Application: PCT/EP2018/051613 WO 20180124
- International Announcement: WO2018/138100 WO 20180802
- Main IPC: C07C7/08
- IPC: C07C7/08 ; B01D3/14 ; B01D3/34 ; B01D11/04 ; B01D11/00

Abstract:
Process for isolating pure 1,3-butadiene from a crude C4 fraction by extractive distillation using a selective solvent, wherein (a) the crude C4 fraction is introduced into a predistillation column, a first low boiler fraction comprising C3-hydrocarbons is taken off as overhead stream, a gaseous C4 fraction is taken off as side stream and a first high boiler fraction is taken off as bottom stream, (b) the gaseous C4 fraction is brought into contact with a selective solvent in at least one extraction column, giving an overhead fraction comprising butanes and butenes and a bottom fraction comprising 1,3-butadiene and selective solvent, (c) crude 1,3-butadiene is desorbed from the bottom fraction in at least one stripping column, with a stripped selective solvent being obtained and the stripped selective solvent being recirculated to the extraction column, and (d) at least part of the crude 1-3-butadiene is fed to a pure distillation column and a second high boiler fraction is separated off and a gaseous purge stream is taken off. Gaseous purge streams from the columns which are necessary in order to keep the concentration of molecular oxygen below a predetermined concentration limit are consolidated with output streams which are in any case provided for discharging other components in the process. The recirculation of the second high boiler fraction to a lower section of the predistillation column creates a further degree of freedom in operation of the pure distillation column.
Public/Granted literature
- US20200339490A1 METHOD FOR OBTAINING PURE 1,3-BUTADIENE Public/Granted day:2020-10-29
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