Invention Grant
- Patent Title: Process to produce long-chain branched polyolefins using dienes
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Application No.: US16289918Application Date: 2019-03-01
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Publication No.: US11041035B2Publication Date: 2021-06-22
- Inventor: John R. Hagadorn , Jo Ann M. Canich , Jingwen Zhang , Peijun Jiang , Britni J. Brobey
- Applicant: ExxonMobil Chemical Patents Inc.
- Applicant Address: US TX Baytown
- Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee: ExxonMobil Chemical Patents Inc.
- Current Assignee Address: US TX Baytown
- Main IPC: C08F2/38
- IPC: C08F2/38 ; C08F4/643 ; C08F4/642 ; C08F210/06 ; C08F236/20 ; C08F210/16 ; C08F10/02 ; C08F2/00 ; C08K5/01 ; C08F4/64 ; C08F4/659 ; C08K5/56

Abstract:
The present disclosure provides methods for producing an olefin polymer including: i) contacting alpha-olefin with a first catalyst system comprising a first non-metallocene catalyst, a first activator, and a reversible chain transfer agent to form a first polymer; ii) contacting the first polymer with a coupling agent in the presence of a catalyst, an activator; and iii) obtaining a second polymer. The present disclosure further provides polymers having a g′vis value from about 0.4 to about 0.8 and a vinyl unsaturation content of 0.8 or greater vinyls/1000 carbons, and preferably low gel content.
Public/Granted literature
- US20190276572A1 Process to Produce Long-Chain Branched Polyolefins Using Dienes Public/Granted day:2019-09-12
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