Systems and methods are provided that facilitate high-sensitivity, carrier-resolved photo-Hall effect measurements. Majority and minority carrier properties can be measured and determined simultaneously. In one aspect, a system and method determine majority carrier type, density and mobility and, with modulated illumination, minority carrier mobility and photocarrier density. In another aspect, a system and method can determine hole and electron mobility, photocarrier density, absorbed photon density, recombination lifetime and diffusion length for hole, electron and ambipolar transport.