An anti-overexposure circuit structure and an electronic device using the same are provided. An anti-overexposure circuit structure includes a first capacitor, a second capacitor, a photo diode, a first switch and a control circuit. The photo diode is coupled to the first capacitor and the second capacitor. The first switch is serially connected to the photo diode. The control circuit is coupled to the first switch and configured to: control the first switch to be turned off when SOC of the first capacitor or SOC of the second capacitor the SOC is lower than a predetermined level. As a result, it can prevent pixel unit of the electronic device from being overexposed.