The invention concerns the field of detergent compositions, in particular detergent compositions for automatic washing, in particular for automatic dishwashing. Therefore, the invention provides a phosphate-free detergent composition comprising at least one non-sulfonated, non-ionic surfactant compound and a non-sulfonated water-soluble copolymer prepared, by polymerisation reaction, in the presence of at least one compound comprising at least one alcohol function, acrylic or methacrylic acid and a compound of formula (I): The invention also concerns the use of this non-sulfonated water-soluble copolymer as an anti-scaling agent or anti-drip agent, and a cleaning method.