An eccentric bush assembly structure of a scroll compressor, in which an orbiting scroll is eccentrically coupled to a rotary shaft of a drive motor, including a bush body rotatably coupled to the orbiting scroll while being pinned to the rotary shaft of the drive motor by an eccentric shaft, the bush body having a friction prevention groove formed in a surface facing a tip surface of the rotary shaft so as not to come into frictional contact with the tip surface.