Invention Grant
- Patent Title: Poly(phenylene ether) copolymer process and compositions
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Application No.: US16497553Application Date: 2018-03-27
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Publication No.: US11111336B2Publication Date: 2021-09-07
- Inventor: Eylem Tarkin-Tas , Huseyin Tas , Mark R. Denniston
- Applicant: SHPP GLOBAL TECHNOLOGIES B.V.
- Applicant Address: NL Bergen op Zoom
- Assignee: SHPP GLOBAL TECHNOLOGIES B.V.
- Current Assignee: SHPP GLOBAL TECHNOLOGIES B.V.
- Current Assignee Address: NL Bergen op Zoom
- Agency: Cantor Colburn LLP
- International Application: PCT/US2018/024432 WO 20180327
- International Announcement: WO2018/194798 WO 20181025
- Main IPC: C08G65/44
- IPC: C08G65/44 ; C08G65/40 ; C08L71/12

Abstract:
A poly(phenylene ether) copolymer of 2-methyl-6-phenylphenol and a dihydric phenol having an absolute number average molecular weight of 1,000 to 10,000 grams/mole is made by polymerization of 2-methyl-6-phenylphenol and a dihydric phenol in the presence of molecular oxygen, a polymerization catalyst comprising a metal ion and at least one amine ligand, and a solvent composed of at least 95 weight percent of a C1-C3 alcohol selected from methanol, ethanol, 1-propanol, and 2-propanol. The poly(phenylene ether) copolymer can be, for example, a copolymer of 2-methyl-6-phenylphenol, 2,2-bis(3,5-dimethyl-4-hydroxyphenol)propane, and optionally 2,6-dimethylphenol. The poly(phenylene ether) copolymer finds utility in curable compositions, cured compositions, and articles.
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