Invention Grant
- Patent Title: Process for making high-strength polylactic acid filament
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Application No.: US16318778Application Date: 2017-07-21
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Publication No.: US11111607B2Publication Date: 2021-09-07
- Inventor: Harm Van Der Werff , Bengisu Corakci , Roman Stepanyan
- Applicant: DSM IP Assets B.V.
- Applicant Address: NL Heerlen
- Assignee: DSM IP Assets B.V.
- Current Assignee: DSM IP Assets B.V.
- Current Assignee Address: NL Heerlen
- Agency: Nixon & Vanderhye P.C.
- Priority: EP16180629 20160721
- International Application: PCT/EP2017/068457 WO 20170721
- International Announcement: WO2018/015528 WO 20180125
- Main IPC: D01F6/92
- IPC: D01F6/92 ; D01F6/62 ; D01D5/06 ; D01D5/12 ; C08L67/04 ; C08G63/08

Abstract:
The present invention relates to a process for making high-strength polylactic acid elongated object comprising the steps of making a solution of polylactic acid in a solvent at a concentration of 5 to 50 mass %; spinning the solution through a spinplate comprising at least 1 spinhole to form a fluid elongated object; cooling the fluid elongated object with a cooling medium to form a solvent-containing gel elongated object; removing at least partly the solvent from the gel elongated object to form a solid elongated object; and drawing the elongated object while applying a draw ratio of at least 2, to form a high strength PLA elongated object, characterized in that the cooling medium has a temperature Tq of less than 0° C. The present invention also relates to gel-spun elongated objects comprising PLA with an IV in the range of 4-40 dl/g, and having a tenacity in N/tex such that Ten≥0.146*IV, as well as gel-spun elongated object having a tenacity and a filament titer in tex (t) such that Ten≥1.40*t −0.3. The invention also relates to articles containing said gel-spun elongated objects.
Public/Granted literature
- US20190284726A1 PROCESS FOR MAKING HIGH-STRENGTH POLYLACTIC ACID FILAMENT Public/Granted day:2019-09-19
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