Invention Grant
- Patent Title: Ethylene-based polymers with new distributions of terminal and internal unsaturations
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Application No.: US16634914Application Date: 2018-07-13
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Publication No.: US11136419B2Publication Date: 2021-10-05
- Inventor: Otto J. Berbee , Stefan Hinrichs , Bharat I. Chaudhary , Teresa P. Karjala , John O. Osby , Jose Ortega
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- Agency: Dinsmore & Shohl LLP
- International Application: PCT/US2018/042141 WO 20180713
- International Announcement: WO2019/027659 WO 20190207
- Main IPC: C08F2/01
- IPC: C08F2/01 ; C08F10/02 ; C08F210/02 ; C08F2/38 ; C08F2/00

Abstract:
A high pressure, free radical polymerization process to form an ethylene-based polymer, the process comprising at least the following step: polymerizing a reaction mixture comprising ethylene, using a polymerization system comprising the following: (A) a reactor configuration comprising at least one reactor that comprises at least two reaction zones, a first reaction zone (reaction zone 1) and an ith reaction zone (where i≥2); wherein the ith reaction zone is the last reaction zone, and wherein i is the total number of reaction zones; (B) at least two ethylene-based feed streams, a first ethylene-based feed stream and an nth ethylene-based feed stream, wherein the first ethylene-based feed stream is sent to the first reaction zone, and the nth ethylene-based feed stream is the last ethylene based feed stream sent to the reactor configuration; wherein n≤i; and RZn/RZ1 does not equal 1.0, where RZ1=mole fraction of make-up ethylene in the first ethylene-based feed stream to the first reaction zone; where RZn=mole fraction of make-up ethylene in the last ethylene-based feed stream sent to the reactor configuration; (C) a control system to control the percentage of the make-up ethylene in the first ethylene-based feed stream, and the percentage of the make-up ethylene in the nth ethylene-based feed stream; and wherein at least one reaction zone receives a CTA make-up feed stream comprising an alpha-olefin, and wherein the alpha-olefin has a chain transfer activity constant (Cs) value ≤0.10, and wherein the chain transfer activity constant (Cs) is measured at 1360 atm, 130° C.
Public/Granted literature
- US20200231712A1 ETHYLENE-BASED POLYMERS WITH NEW DISTRIBUTIONS OF TERMINAL AND INTERNAL UNSATURATIONS Public/Granted day:2020-07-23
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