The present application relates to a positive electrode plate and an electrochemical device. The positive electrode plate includes a current collector, a positive active material layer and a safety coating disposed between the current collector and the positive active material layer, the safety coating including a polymer matrix and a conductive material, wherein the polymer matrix is fluorinated polyolefin and/or chlorinated polyolefin, and when the safety coating and the positive active material layer are collectively referred to as a positive film layer, the positive film layer includes Na ions and/or K ions at a content of 100 ppm or more, and has an absorption peak at 1646 cm−1 in infrared absorption spectrum. The positive electrode plate may improve safety performance at elevated temperature of the electrochemical device by quickly disconnecting the circuit at high temperature conditions or when an internal short circuit occurs.