The present disclosure relates to a multilayer film including polyalkylene carbonate, and more particularly to a multilayer film including a core layer prepared by blending polyalkylene carbonate and an ethylene vinyl acetate copolymer in a predetermined ratio, and an outer layer of polyolefin. The multilayer film does not have delamination behavior because two layers are adhered each other with a simple process without an additional step for introducing an oxygen-barrier layer even without adhesive or tie layers, and has an excellent oxygen barrier property. In addition, since an additional process for imparting barrier properties and a separate adhesive or tie layer are not required in the manufacturing method, the cost can be reduced and the layer structure can be simplified, which may greatly reduce the manufacturing cost.