A solar radiation shielding laminated structure, having high visible light transmission property and solar radiation shielding property, low haze value, and high environmental stability with inexpensive production cost, using solar radiation shielding fine particles having high visible light transmission property and excellent solar shielding property and weather resistance, and provides a solar radiation shielding laminated structure in which an interlayer is sandwiched between two laminated sheets; the interlayer having, as an intermediate film, one or more kinds selected from a resin sheet containing solar radiation shielding fine particles and a resin film containing solar radiation shielding fine particles, the laminated sheets being selected from a sheet-glass not containing solar radiation shielding fine particles and a resin board not containing solar radiation shielding fine particles; wherein the solar radiation shielding fine particles are solar radiation shielding fine particles containing calcium lanthanum boride fine particles represented by general formula CaxLa1-xBm.