A gripping assembly for a capping head for applying caps on containers, as well as a capping head, are provided. The gripping assembly comprises a hollow body longitudinally extending along a vertical axis and internally defining a seat delimited at its lower end by an inlet mouth for the introduction of a cap. An ejector member is housed inside the hollow body such that the ejector member is free to slide axially. The gripping assembly further comprises a suspension member made of magnetic material or magnetizable material, and the ejector member carries a first magnetic element that interacts with the suspension member to determine a suspension condition of the ejector member. The magnetic interaction between the first magnetic element and the suspension member is such that the suspension condition is determined only when the ejector member is brought in close proximity of or, in contact with, the suspension member.