Multi-barrier bottles having tabbed preforms, as well as methods of forming the same are disclosed. A tabbed preform includes an elongate body extending into a cavity of a first barrier, where the cavity is defined by at least one piece having a recess therein. The tabbed preform further includes at least one preform extension piece extending from the elongate body at a predetermined distance from a top surface of the elongate body. The at least one preform extension piece is sized and shaped to correspond to a size and a shape of the recess.